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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

SYNTHESIS OF Nb2AlC MAX-PHASE IN KBr PROTECTIVE MELT

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PII
10.31857/S0044457X24120201-1
DOI
10.31857/S0044457X24120201
Publication type
Article
Status
Published
Authors
I. A Nagornov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
M. V. Kozlova
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 12
Pages
1882-1891
Abstract
The possibility of synthesis of Nb2AlC MAX-phase composition at varying temperature (900–1250℃) and molar ratio of initial reagents (powders of niobium, aluminum, carbon, as well as KBr salt, which performed a protective function in obtaining the target compound) was studied. By XRD it was found that at low synthesis temperatures (900–1100℃) only intermediate products are obtained, and at the synthesis temperature of 900℃ metallic niobium is also present. SEM and EDX-mapping data confirm the formation of MAX-phase at higher synthesis temperatures of 1200 and 1250℃. The effectiveness of decreasing the content of carbon in the initial mixture and increasing the aluminum content is shown. The thermal behavior in air current of the products obtained at temperatures of 900 and 1250℃ was studied.
Keywords
МАХ-фаза синтез в расплаве соли
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

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