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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Thermodynamic Properties of Lutetium Stannate Lu2Sn2O7 in the Temperature Range 0–1871 K

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PII
10.31857/S0044457X24080068-1
DOI
10.31857/S0044457X24080068
Publication type
Article
Status
Published
Authors
M. A. Ryumin
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 8
Pages
1135-1143
Abstract
Lutetium stannate with a pyrochlore structure was synthesized using solid state reaction route. The heat capacity of the polycrystalline Lu2Sn2O7 in the temperature range 7.99–1871 K was measured by adiabatic and differential scanning calorimetry methods. Entropy, enthalpy change, and derived Gibbs energy were calculated from the smoothed heat capacity data. The Gibbs free energy of Lutetium stannate from simple substances was estimated, using the ΔfS°(Т) values obtained in this work and the ΔfH°(Т) values from the literature. The temperature dependence of the cubic crystal lattice parameter and the value of the coefficient of thermal expansion in the temperature range 300–1273 K were determined by high-temperature X-ray diffraction.
Keywords
станнаты лютеций теплоемкость термическое расширение
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
12

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