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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

SURFACE DEGRADATION OF CERAMIC MATERIAL BASED ON THE ZrB-HfB-SiC SYSTEM UNDER THE INFLUENCE OF A SUBSONIC FLOW OF DISSOCIATED NITROGEN CONTAINING 5 mol. % CO

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PII
S3034560X25100191-1
DOI
10.7868/S3034560X25100191
Publication type
Article
Status
Published
Authors
E.P. Simonenko
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
A.V. Chaplygin
  • Affiliation: Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences
A.S. Lysenkov
  • Affiliation: A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
I.A. Nagornov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
I.V. Lukomskii
  • Affiliation: Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences
A.S. Mokrushin
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
N.P. Simonenko
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
A.F. Kolesnikov
  • Affiliation: Ishlinskii Institute of Problems of Mechanics of the Russian Academy of Sciences
N.T. Kuznetsov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 70 / Issue number 10
Pages
1417-1427
Abstract
Ultra-high-temperature ceramics based on zirconium and hafnium diborides are of great scientific and technical interest, as they can be very promising, including as components of descent vehicles for space exploration. To study the behavior of these ceramics under the influence of high-speed flows of dissociated gases of complex composition and to determine the effect of modifying the ZrB-HfB-SiC system with carbon nanotubes, the process of surface degradation under the influence of a subsonic flow of dissociated nitrogen containing 5 mol. % CO was examined. Despite the relatively low CO content in the nitrogen plasma, the surface oxidation process dominated the conversion of the initial ZrB/HfB into solid solutions based on monocarbonitrides of these metals. In this case, it was noted that a protective layer of silicate glass does not form on the surface, unlike similar materials under the influence of subsonic flows of dissociated air at temperatures
Keywords
UHTC HfB ZrB SiC деградация индукционный плазмотрон N—CO-плазма
Date of publication
01.10.2025
Year of publication
2025
Number of purchasers
0
Views
61

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