RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

SUBSTITUTION OF PRASEODYMIUM FOR CADMIUM AND LEAD IN THE PrMoO STRUCTURE

PII
S0044457X25050047-1
DOI
10.31857/S0044457X25050047
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 70 / Issue number 5
Pages
652-659
Abstract
Solid solutions based on fluorite-like phase in systems PrMeMoO, where Me = Cd, Pb, were obtained by solid-phase synthesis from metal oxides. The phase content after calcination at 1000°C was studied by X-ray diffraction, the substitution limits and the dependences of the unit cell parameter on the composition of the systems were determined. The parameters of the crystal structure of solid solutions were specified by the Rietveld method. The influence of magnesium oxide additives on the sinterability of cadmium-containing solid solutions has been established. Isomorphous substitution of praseodymium by lead and cadmium leads to a decrease in the conductivity value of the samples in the studied systems.
Keywords
изоморфные замещения молибдат празеодима структура NdMoO гетеровалентные замещения электропроводность
Date of publication
05.03.2025
Year of publication
2025
Number of purchasers
0
Views
12

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