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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Synthesis and properties of LiNiO2 close to stoichiometric composition obtained by combined synthesis method

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PII
S0044457X25010055-1
DOI
10.31857/S0044457X25010055
Publication type
Article
Status
Published
Authors
R. I. Korneykov
  • Affiliation: Sakhalin State University
Volume/ Edition
Volume 70 / Issue number 1
Pages
42-53
Abstract
This study presents the synthesis and characterisation of lithium nickelate LiNiO₂ with near-stoichiometric composition prepared by a combined method. LiNiO2 exhibits high electrochemical properties including a theoretical capacity of 250–270 mA/g, making it a promising cathode material for lithium-ion batteries as an alternative to LiCoO2. However, the commercial use of LiNiO₂ is limited by the difficulty in achieving stoichiometric composition and the high cost of conventional synthesis methods. Using X-ray phase analysis and spectrometry, we identified the phases formed and determined their chemical composition. Electron microscopy and Brunauer-Emmett-Teller (BET) techniques were used to investigate the structure and morphology. The developed process scheme led to the preparation of lithium nickelate with the composition Li(0.98)Ni(1.02)O₂, providing the formation of nanoscale samples with high specific surface area and improved electrochemical performance. These results emphasise the potential of LiNiO2 as a competitive cathode material for lithium-ion batteries.
Keywords
литий-ионные аккумуляторы катод никелат лития золь-гель твердофазный синтез
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
11

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