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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

HYDROTHERMAL SYNTHESIS OF AQUEOUS SOLS OF NANOCRYSTALLINE HAFNIUM DIOXIDE STABILIZED BY LACTIC ACID AND THEIR ENZYME-LIKE ACTIVITIES

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PII
10.31857/S0044457X24120092-1
DOI
10.31857/S0044457X24120092
Publication type
Article
Status
Published
Authors
T. V. Khamova
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    International Research University Higher School of Economics
M. V. Kozlova
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    International Research University Higher School of Economics
Volume/ Edition
Volume 69 / Issue number 12
Pages
1763-1773
Abstract
A method for obtaining aqueous sols of nanocrystalline hafnium dioxide (with hydrodynamic diameter 20-35 nm) stabilised by lactic acid (lactate ions) and characterised by high colloidal stability (zeta-potential -29 mV) has been developed. The method is based on the hydrothermal treatment of a previously obtained complex compound of hafnium with lactic acid in the presence of urea at temperatures of 180 and 220 degrees Celsius for 48 and 96 h. By chemiluminescence analysis in the model reaction of luminol oxidation it was found that nanocrystalline hafnium oxide in the composition of sols exhibits dose-dependent pro-oxidant activity towards hydrogen peroxide and thus exhibits peroxidase-like properties.
Keywords
наноматериалы нанозимы коллоидные растворы диоксид гафния хемилюминесценция прооксидант пероксидазоподобная активность
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
11

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