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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

SYNTHESIS OF Ti2AlC IN KBr MELT: EFFECT OF TEMPERATURE AND COMPONENT RATIO

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PII
10.31857/S0044457X24110128-1
DOI
10.31857/S0044457X24110128
Publication type
Article
Status
Published
Authors
E. P. Simonenko
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
M. V. Kozlova
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 11
Pages
1631-1642
Abstract
MAX phases of various compositions have recently found increasing application due to their multilayer structure and properties that are characteristic of ceramic materials and metals. Therefore, the development of easily scalable methods for obtaining these compounds characterized by increased phase purity is of great importance. Within the framework of the work the influence on the composition and properties of such MAX phase, as Ti2AlC, conditions of its preparation with the use of protective melt of salts (on the example of KBr), in particular, ratios ofinitial reagents (n(Ti) : n(Al) : n(C)), temperature and duration of heat treatment has been studied. It was found that at the temperature 1100∘C the highest yield of Ti2AlC (94.4%) can be obtained in the case of using the molar ratio n(Ti) : n(Al) : n(C) = 2 : 1.1 : 0.9. It is shown that the use of synthesis temperatures from 900 to 1100∘C changes the content of the target MAX phase insignificantly(from 94 to 96%), the maximum content of Ti2AlC was found in the case of obtaining a sampleat the temperature 1000∘C. The influence of synthesis temperature (900, 1100 and 1200∘C) on microstructure, thermal behavior in air current and the value of electron work function was alsostudied.
Keywords
МАХ-фаза синтез в расплаве солей окисление работа выхода электрона
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
11

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