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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Mixed Yttrium and Dysprosium Lactates as First Example of Rare-Earth Hydrogen-Bonded Organic Framework Solid Solutions

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PII
10.31857/S0044457X24100057-1
DOI
10.31857/S0044457X24100057
Publication type
Article
Status
Published
Authors
M. V. Golikova
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    Lomonosov Moscow State University
Volume/ Edition
Volume 69 / Issue number 10
Pages
1391-1404
Abstract
For the first time, molecular solid solutions of yttrium and dysprosium lactates of [Y1-xDyx(C3H5O3)3(H2O)2] composition, where x = 0, 0.01, 0.1, 0.5, 0.8, and 1, have been obtained. These can be considered the first solid solutions of rare-earth hydrogen-bonded organic framework (M-HOF). The obtained compounds were analyzed using a set of instrumental methods, including X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), infrared (IR), and Raman spectroscopy. It has been shown that the unit cell volume of the lactate solid solutions linearly depends on their cationic composition. It has been established that changes in the cationic composition of the solid solutions result in a monotonic shift of the lines in the Raman spectra corresponding to Ln–O vibrations (151–158 cm–1). It has been demonstrated that the obtained compounds can be single-molecule magnets with an energy barrier of up to 108 K.
Keywords
мономолекулярные магнетики лактаты РЗЭ твердые растворы координационные полимеры
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
12

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