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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Carboxonium derivatives of closo-decaborate anion [2,6-B10H8O2CC6H4R]– based on aromatic carboxylic acids: synthesis and physicochemical properties

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PII
10.31857/S0044457X24090043-1
DOI
10.31857/S0044457X24090043
Publication type
Article
Status
Published
Authors
А. V. Kolbunova
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 9
Pages
1245-1253
Abstract
The series of carboxonium derivatives of the closo-decaborate anion of the general form [2,6-B10H8O2CC6H4R]–, R=F, CH3, C3H7, C6H5 was obtained. To obtain the target systems, the interaction of the [B10H11]– anion with aromatic carboxylic acids was used. This process took place in two stages through the formation of a monosubstituted derivative of the general form [2-B10H9OC(OH)C6H4R]–, R=F, CH3, C3H7, C6H5, followed by intramolecular cyclization, leading to the formation of the target disubstituted carboxonium derivatives. The structure of the [2,6-B10H8O2CC6H4-C6H5] anion was confirmed by X-ray diffraction analysis. The resulting carboxonium derivatives are capable of protonation to form neutral systems of the general form [2,6-B10H8O2CC6H4R(Hfac)]0, R=F, CH3, C3H7, C6H5. When a protonated carboxonium derivative of acetonitrile is added to a solution, a trisubstituted derivative of the general form [B10H7O2CC6H4R(NCCH3)]0 is formed.
Keywords
клозо-бораты карбоксониевые производные кластеры бора
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
4

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