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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

On phosphine-containing gold(I) complexes in solutions in connection with their biological applications

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PII
10.31857/S0044457X24060129-1
DOI
10.31857/S0044457X24060129
Publication type
Article
Status
Published
Authors
I. V. Mironov
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 6
Pages
899-906
Abstract
Some transformations involving AuCl(PPh3) in CH3CN/H2O solution are considered and a comparison is made with known data for auranofin. Interaction with GSH leads to the formation of a binuclear (GSH)[Au(PPh3)]2 (at CGSH/CAu < 0.5) or mononuclear Au(GSH)(PPh3) (CGSH/CAu > 0.5) complex; PPh3 substitution is not observed. Interaction with BSA leads to Cl– substitution. A cyclic voltammetry study showed the presence of several peaks of irreversible oxidation of AuCl(PPh3) and complexes with GSH.
Keywords
соединения золота(I) фосфины комплексообразование тиолы
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

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