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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Application Of Vanadyl Alkoxoacetylacetonate In Formation Of v2O5 Electrochromic Films

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PII
10.31857/S0044457X24040177-1
DOI
10.31857/S0044457X24040177
Publication type
Article
Status
Published
Authors
Ph. Yu. Gorobtsov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 4
Pages
624-633
Abstract
Crystal structure, morphology and electrochromic properties of V2O5 film, prepared using vanadyl alkoxoacetylacetonate as precursor, were studied. We have shown that the obtained vanadium pentoxide contains significant amount of V4+ cations, which is indicated by low electron work function among other things. This results in material possessing anodic electrochromism – coloring upon oxidation – with rapid bleaching process (1 s upon necessary potential application). Anodic coloration is observed in the whole visible light spectrum, as well as in near IR region up to 1100 nm. Obtained data show high prospects for approach to formation of V2O5-based films using vanadyl acetylacetonate as precursor and application of such films as components of smart windows and displays, optical properties of which could be controlled by electrical current application.
Keywords
оксид ванадия пентаоксид ванадия электрохромизм алкоксоацетилацетонат электрохромные материалы
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
15

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