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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Crystallization at "Soft" Chemistry Conditions of New Inorganic Fluoride Nanomaterials and Their Application Prospects

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PII
10.31857/S0044457X24030027-1
DOI
10.31857/S0044457X24030027
Publication type
Article
Status
Published
Authors
L. B. Gulina
  • Affiliation: Saint Petersburg State University
Volume/ Edition
Volume 69 / Issue number 3
Pages
272-285
Abstract
Peculiarities of formation and growth of crystals of metal fluorides MF2 (where M — Ca, Sr, Pb) and MF3 (where M — Sc, La, Ln) as a result of interaction between components of an aqueous solution of metal salt and gaseous hydrogen fluoride at planar interface at room temperature are considered. Compounds with different crystal structures: PbF2 (pr. gr. Pnma, Fm3m), ScF3 (pr. gr. Pm3m, P6/mmm), LaF3 (pr. gr. P3c1) were chosen as model objects. The factors that have a significant influence on the morphology, size, and ordering of the formed crystals have been determined. The possibility of synthesis of 1D and 2D crystals is shown for some compounds. Probable fields of application of nanomaterials based on synthesized compounds are analyzed. The conclusion is made about the possibility of the interface technique developing for the design of new solid electrolytes, optically active materials, and functional coatings.
Keywords
нанокристаллы граница раздела раствор–газ ионные проводники
Date of publication
15.03.2024
Year of publication
2024
Number of purchasers
0
Views
41

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