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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Zinc(II) complexes with thiadiazole derivatives-1,3,4

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PII
10.31857/S0044457X24020061-1
DOI
10.31857/S0044457X24020061
Publication type
Article
Status
Published
Authors
K. K. Turgunov
  • Affiliation:
    Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Ripublic of Uzbekistan
    Turin Polytechnic University in Tashkent
K. Sh. Khusenov
  • Affiliation: Institute of Bioorganic Chemistry of the Academy of Sciences of Uzbekistan
Volume/ Edition
Volume 69 / Issue number 2
Pages
193-202
Abstract
Zn(II) complexes of the composition [ZnLn2X2] and [ZnLn3(NO3)2] were synthesized, where n = 1, 2; X=Cl, Br, I; L1=2-aminothiadiazole-1,3,4, L2=2-amino-5-methylthiadiazole-1,3,4. The obtained complexes were studied by elemental analysis methods, IR and 1H NMR spectroscopy. The structure of the [ZnL22Br2] complex was determined by the RSA method (CIF file CCDC No. 2251742). The ligand molecules of 2-amino-5-R-thiadiazoles-1,3,4 (R = –H, –CH3) are coordinated monodentately by an endocyclic nitrogen atom located in the α-position to the amino group. The polyhedron of the central atom of halide complexes is a slightly distorted tetrahedron, in the coordination sphere of which two halide atoms and two endocyclic nitrogen atoms are located. During complexation in the spectrum of the solution of the [ZnL22Br2] complex, coordinated L2 ligands undergo amino-imine tautomerization into a heterocyclic amine with a nitrogen atom in a heterocycle. The polyhedron of the central atom for nitrate complexes is a slightly distorted trigonal bipyramide, in the coordination sphere of which three nitrogen atoms of ligands are located in the equatorial plane and two oxygen atoms of two nitrate anions in the axial position.
Keywords
2-аминотиадиазол-1,3,4 2-амино-5-метилтиадиазол-1,3,4 комплексы цинка рентгеноструктурный анализ полиэдры
Date of publication
15.02.2024
Year of publication
2024
Number of purchasers
0
Views
50

References

  1. 1. Serban Georgeta, Stanasel Oana, Serban Eugenia, Bota Sanda // Drug Des Devel Ther. 2018. V. 12. № 5. P. 1545. https://doi.org/10.2147/DDDT.S155958
  2. 2. Karapetyan L.V., Tokmajyan G.G. // Russ. J. Gen. Chem. 2023. V. 93. № 3. P. 506. https://doi.org/10.1134/S1070363223030076
  3. 3. Nikiforova M.E., Lutsenko I.A., Kiskin M.A. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 9. P. 1343. https://doi.org/10.1134/S0036023621090102
  4. 4. Wang Y.F., Zhang S.Q., Feng Y.X., Wang L.Y. // Russ. J. Gen. Chem. 2021. V. 91. № 8. P. 1566. https://doi.org/10.1134/S1070363221080193
  5. 5. Никифорова С.Е., Кубасов А.С., Белоусова О.Н. и др. // Журн. неорган. химии. 2023. Т. 68. № 6. С. 832. https://doi.org/10.31857/S0044457Х2260219Х
  6. 6. Kalanithi M., Rajarajan M., Tharmaraj P., Johnson Raja S. // Med. Chem. Res. 2015. V. 24. № 4. P. 1578. https://doi.org/10.1007/s00044-014-1224-5
  7. 7. Kadirova Sh.A., Ishankhodzhaeva M.M., Parpiev N.A. et al. // Russ. J. Gen. Chem. 2008. V. 77. № 12. P. 2398. https://doi.org/10.1134/S1070363208120177
  8. 8. Umirov F.E., Shodikulov J.M., Aslonov A.B., Sharipov S.Sh.// Obog. rud. 2023/.V. 4. P. 25. https://www.doi.org/10.17580/or.2023.04.05
  9. 9. Chikineva T.Yu., Koshelev D.S., Medved`ko A.V. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 2. P. 170. https://doi.org/10.1134/S0036023621020054
  10. 10. Batyrenko A.A., Mikolaichuk O.V., Ovsepyan G.K. et al. // Russ. J. Gen. Chem. 2021. V. 91. № 4. P. 666. https://doi.org/10.1134/S1070363221040149
  11. 11. Li R.Y., Li Y.J., Lu X.H. et al. // Russ. J. Coord. Chem. 2020. V. 46. № 12. P. 26. https://doi.org/10.1134/S1070328420010042
  12. 12. Zahoor Ayesha, Imtiaz-ud-Din, Andleeb Sohaila et al. // J. Coord. Chem. 2021. V. 74. № 12. P. 1978. https://doi.org/10.1080/00958972.2021.1945046
  13. 13. Yong-Hui Zhou, Dong Jiang, You-Xuan Zheng // J. Organomet. Chem. 2018. V. 876. № 12. P. 26. https://doi.org/10.1016/j.jorganchem.2018.09.008
  14. 14. Umarov B.B., Ishankhodzhaeva M.M., Khusenov K.Sh. et al. // Russ. J. Org. Chem. 1999. V. 35. № 4. P. 599.
  15. 15. Uvarova M.A., Nefedov S.E. // Russ. J. Inorg. Chem. 2021. V. 66. № 11. P. 1660. https://doi.org/10.1134/S0036023621110218
  16. 16. Ligin Chen, Huihui Duan, Xinyu Zhang et al. // J. Heter. Chem. 2018. V. 55. № 8. P. 1978. https://doi.org/10.1002/jhet.3238
  17. 17. Abdelhakim Laachir, Salaheddine Guesmi, El Mostafa Ketatni et al. // J. Mol. Struct. 2020. V. 74. № 12. P. 1978. https://doi.org/10.1016/j.molstruc.2020.128533
  18. 18. Song Ye, Ji Yu-Fei, Kang MiN-Yan, Liu Zhi-Liang // Acta Crystallogr., Sect. E. 2012. V. 68. № 5. P. 772. https://doi.org/10.1107/S1600536812020995
  19. 19. Geng Ying, Zhang Wen, Song Jiang-Feng et al. // Inorg. Chim. Acta. 2021. V. 528. № 12. P. 120596. https://doi.org/10.1016/j.ica.2021.120596
  20. 20. Matveev E.Yu., Novikov I.V., Kubasov A.S. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 2. P. 187. https://doi.org/10.1134/S0036023621020121
  21. 21. Lavrenova L.G., Dyukova I.I., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. № 1. P. 30. https://doi.org/10.1134/S0036023620010106
  22. 22. Yousif Emad, Majeed Ahmed, Al-Sammarrae Khulood et al. // Arab. J. Chem. 2017. V. 10. № 5. P. 1639. https://doi.org/10.1016/j.arabjc.2013.06.006
  23. 23. Kodirov S., Mukhiddinov B. et. al. // E3S Web of Conf. 2023. V. 417. P. 02010. https://doi.org/10.1051/e3sconf/202341702010
  24. 24. Sargsyan S.H., Sargsyan T.S., Agadjanyan I.G. et al. // Russ. J. Gen. Chem. 2021. V. 91. № 2. P. 223. https://doi.org/10.1134/S1070363221020109
  25. 25. Gaponik P.N., Ivashkevich O.A., Krasitskii V.A. et al. // Russ. J. Gen. Chem. 2002. V. 72. № 9. P. 1457. https://doi.org/10.1023/A:1021646400922
  26. 26. Markosyan A.I., Ayvazyan A.S., Gabrielyan S.H. et al. // Russ. J. Gen. Chem. 2023. V. 93. № 3. P. 485. https://doi.org/10.1134/S1070363223030040
  27. 27. Önkol T., Doğruer D.S., Uzun L. et al. // J. Enzyme Inhibition Med. Chem. 2008. V 23. № 2. Р. 277. https://doi.org/10.1080/14756360701408697
  28. 28. Yuhang He, Jingwen Chen, Xinran Yu et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 8. P. 1264. https://doi.org/10.1134/S0036023622080162
  29. 29. Popov L.D., Borodkin S.A., Kiskin M.A. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 1. P. 9. https://doi.org/10.1134/S1070328421110038
  30. 30. Garnovskii A.D., Burlov A.S., Vasil’chenko I.S. et al. // Russ. J. Coord. Chem. 2010. V. 36. № 2. P. 81. https://doi.org/10.1134/S1070328410020016
  31. 31. Khusenov K.Sh., Umarov B.B., Ishankhodzhaeva M.M. et al. // Russ. J. Coord. Chem. 1997. V. 23. № 8. P. 555.
  32. 32. Ishankhodzhaeva M.M., Khusenov K.Sh., Umarov B.B. et al. // Russ. J. Inorg. Chem. 1998. V. 43. № 11. P. 1709.
  33. 33. Khusenov K.Sh., Umarov B.B., Ishankhodzhaeva M.M. et al. // Russ. J. Inorg. Chem. 1998. V. 43. № 12. P. 1841.
  34. 34. Rigaku Oxford Diffraction. CrysAlisPRO; Yarnton: England, 2018. Search in Google Scholar
  35. 35. Sheldrick G.M. SADABS. Program for Scaling and Correction of Area Detector Data (Univ. of Göttingen, Göttingen, Germany, 1997).
  36. 36. Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. V. 71. № 1. P. 3. https://doi.org/10.1107/s2053229614024218
  37. 37. Накомото К. ИК-спектры и спектры КР неорганических и координационных соединений. Пер. с англ. M.: Мир, 1991. 536 с.
  38. 38. Kadirova Sh.A., Nuralieva G.A., Alieva M.A. et al. // Russ. J. Gen. Chem. 2005. V. 75. № 12. P. 1962. https://doi.org/10.1007/s11176-006-0022-2
  39. 39. Данилова Е.А., Меленчук Т.В., Трухина О.Н. и др. // Макрогетероциклы/Macroheterocycles. 2010. V. 1. № 3. С. 68. https://doi.org/10.6060/mhc2010.1.68
  40. 40. Umarov B.B., Avezov K.G., Tursunov M.A. et. al. // Russ. J. Coord. Chem. 2014. V. 40. № 7. P. 473. https://doi.org/10.1134/S1070328414070094
  41. 41. Киперт Д. Неорганическая стереохимия. М.: Мир, 1975. 280 с.
  42. 42. Хусенов К.Ш., Алиев Т.Б., Бахронова О.Ж. // Int. J. Adv. Technol. Natural Sci. 2022. V. 3. № 4. С. 25. https://doi.org/10.24412/2181-144X-2022-4-25-35
  43. 43. Beatriz C., Verónica G., Ana E. Platero-Prats et al. // Dalton Trans. Royal Soc. Chem. 2008. P. 2832. https://doi.org/ 10.1039/b801115j
  44. 44. Lynch D.E. // Acta Crystallogr., Sect. C. 2001. V. 57. Р. 1201. https://doi.org/10.1107/S0108270105040126
  45. 45. Kadirova Sh.A., Ishankhodzhaeva M.M., Parpiev N.A. et al. // Russ. J. Gen. Chem. 2007. V. 77. № 10. P. 1799. https://doi.org/10.1134/S1070363207100210
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