- PII
- 10.31857/S0044457X23601098-1
- DOI
- 10.31857/S0044457X23601098
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 9
- Pages
- 1287-1292
- Abstract
- New bis-chelate cobalt(II) complex [Co(DPG)2(DMF)2] (1), where DPG is N-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex 1 has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process ( = –1.70 V vs Ag/AgNO3, 1 × 10–2 М in CH3CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.
- Keywords
- α-фосфино-α-аминокислота α-дифенилфосфорилглицинат комплекс кобальта рентгеновская дифракция циклическая вольтамперометрия
- Date of publication
- 01.09.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 37
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