- PII
- 10.31857/S0044457X22700167-1
- DOI
- 10.31857/S0044457X22700167
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 3
- Pages
- 363-372
- Abstract
- The formation of mixed-ligand complexes of various compositions in the Zn–L-histidine (His)–L-ornithine (Orn) system has been studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log K, ΔrG0 ΔrH, ΔrS) of the reactions of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) have been calculated. Based on the comparative analysis of thermodynamic parameters, the most probable method for the coordination of amino acid residues in mixed complexes has been proposed.
- Keywords
- смешанолигандное комплексообразование гистидин орнитин калориметрия цинк дентатность
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
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