- PII
- 10.31857/S0044457X22602310-1
- DOI
- 10.31857/S0044457X22602310
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 6
- Pages
- 768-773
- Abstract
- The reaction of nitrile derivatives of closo-dodecaborate anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr) with water has yielded a series of (Et4N)[B12H11NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by 11В, 1Н, 13С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B12H11(Z-NH=C(OH)nC3H7)]− and [B12H11(E-NH–C(O)nC3H7)]2− anions have been determined by X-ray single-crystal diffraction.
- Keywords
- <i>клозо</i>-додекабораты нитрилиевые производные иминолы амиды
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 12
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