RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Synthesis of Silver Nanoclusters and Nanoparticles in the Medium of Hyperbranched Polyester Polyamine, and the Morphology and Aggregation Properties of the Metal–Polymer Nanocomposite

PII
10.31857/S0044457X22601857-1
DOI
10.31857/S0044457X22601857
Publication type
Status
Published
Authors
Volume/ Edition
Volume 68 / Issue number 5
Pages
672-681
Abstract
A procedure was developed for the single-step synthesis of a metal–polymer nanocomposite based on silver nanoparticles and second-pseudogeneration superbranched polyester functionalized along the periphery with 3-[(2-aminoethyl)amino]propionate. Under the conditions of the synthesis in the medium of H2O or DMSO, hyperbranched polyester decorated with ethylenediamine moieties can act as both a reductant of the nanoscale silver state and a stabilizer of it. The synthesized composite nanomaterial is formed by aggregates of hyperbranched polyester polyamine doped with Ag(0) nanoclusters and nanoparticles of spheroidal symmetry with a face-centered cubic crystal lattice. The hydrodynamic diameter of aggregates and the diameter of particles increase with increasing molar ratio and are 34–90 and 7–14 nm, respectively.
Keywords
наночастицы серебра сверхразветвленные полимеры композитные материалы
Date of publication
01.05.2023
Year of publication
2023
Number of purchasers
0
Views
46

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