- PII
- 10.31857/S0044457X22601456-1
- DOI
- 10.31857/S0044457X22601456
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 2
- Pages
- 203-208
- Abstract
- Cs2MoO4 and Li1.9Cs0.1MoO4 crystals were grown from melt by the low-thermal-gradient Czochralski technique. The standard formation enthalpy of cesium molybdate Cs2MoO4 was measured by solution calorimetry. The heat capacity of Li1.9Cs0.1MoO4 was measured by differential scanning calorimetry (DSC) in the temperature range 320–710 K. The lattice enthalpy of Cs2MoO4 was calculated using the Born-Haber cycle. Cesium molybdate was shown to be thermodynamically stable to decomposition into constituent simple oxides (Cs2O and MoO3), which made it promising for application. Li1.9Cs0.1MoO4 experienced no phase transitions in the temperature range 320–710 K.
- Keywords
- молибдат цезия стандартная энтальпия образования энтальпия решетки теплоемкость калориметрия растворения ДСК-калориметрия
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 11
References
- 1. Simonenko T.L., Bocharova V.A., Simonenko N.P. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1779. https://doi.org/10.1134/S0036023621120160
- 2. Bekker T.B., Coron N., Danevich F.A. et al. // Astroparticle Phys. 2016. V. 72. P. 38. https://doi.org/10.1016/j.astropartphys.2015.06.002
- 3. Barinova O., Sadovskiy A., Ermochenkov I. // J. Cryst. Growth. 2017. V. 468. P. 365. https://doi.org/10.1016/j.jcrysgro.2016.10.009
- 4. Fattakhova Z.A., Vovkotrub E.G., Zhknarova G.S. // Russ. J. Inorg. Chem. 2021. V. 66. P. 35. https://doi.org/10.1134/S0036023621010022
- 5. Teng T., Xiao L., Shen L. et al. // Appl. Surf. Sci. 2022. V. 601. P. 154101. https://doi.org/10.1016/j.apsusc.2022.154101
- 6. Isaenko L.I., Korzhneva K.E., Khyzhin O.Y. et al. // J. Solid State Chem. 2019. V. 277. P. 786. https://doi.org/10.1016/j.jssc.2019.07.047
- 7. Steblevskaya N.I., Belobeletskaya M.V., Yarovaya T.P. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 245. https://doi.org/10.1134/S0036023622020164
- 8. Kim H., Pandey I.R., Khan A. et al. // Cryst. Res. Technol. 2019. V. 54. P. 1900079. https://doi.org/10.1002/crat.201900079
- 9. Son J.K., Pandey I.R., Kim H.J. et al. // IEEE Trans. Nucl. Sci. 2018. V. 65. P. 2120. https://doi.org/10.1109/TNS.2018.2818330
- 10. Papynov E.K., Shichalin O.O., Belov A.A. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1434. https://doi.org/10.1134/S0036023621090114
- 11. Smith A.L., Kauric G., van Eijck L. et al. // J. Solid State Chem. 2017. V. 253. P. 89. https://doi.org/10.1016/j.jssc.2017.05.032
- 12. Matskevich N.I., Semerikova A.N., Shlegel V.N. et al. // J. Alloys Compd. 2021. V. 850. P. 156683. https://doi.org/10.1016/j.jallcom.2020.156683
- 13. Kasimkin P.V., Moskovskih V.A., Vasiliev Y.V. // J. Cryst. Growth. 2014. V. 390. P. 67. https://doi.org/10.1016/j.jcrysgro.2013.12.027
- 14. Volokitina A., Loiko P., Pavlyuk A. et al. // Opt. Mater. Express. 2020. V. 10. P. 2356. https://doi.org/10.1364/OME.400894
- 15. Matiutin A.S., Kovalenko N.A., Uspenskaya I.A. // J. Chem. Eng. Data. 2022. V. 67. P. 984. https://doi.org/10.1021/acs.jced.1c00849
- 16. Druzhinina A.I., Tiflova L.A., Monayenkova A.S. et al. // Russ. J. Phys. Chem. A. 2019. V. 93. P. 2101. https://doi.org/10.1134/S0036024419110098
- 17. Matskevich N.I., Kellerman D.G., Gelfond N.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 720. https://doi.org/10.1134/S0036023620050150
- 18. Tsvetkov D.S., Sereda V.V., Malyshkin D.A. et al. // Chim. Techno Acta. 2021. V. 7. P. 42. https://doi.org/10.15826/CHIMTECH.2020.7.2.01
- 19. Matskevich N.I., Wolf Th., Vyazovkin I.V. et al. // J. Alloys Compd. 2015. V. 628. P. 126. https://doi.org/10.1016/j.jallcom.2014.11.220
- 20. Matskevich N.I., Chuprova M.V., Punn R. et al. // Thermochim. Acta. 2007. V. 459. P. 125. https://doi.org/10.1016/j.tca.2007.03.015
- 21. Matskevich N.I., Krabbes G., Berasteguie P. // Thermochim. Acta. 2003. V. 397. P. 97. https://doi.org/10.1016/S0040-6031 (02)00330-1
- 22. Kilday M.V. // J. Res. Nat. Bur. Stand. 1980. V. 85. P. 467.
- 23. Gunther C., Pfestorf R., Rother M. et al. // J. Therm. Anal. Calorim. 1988. V. 33. P. 359. https://doi.org/10.1007/BF01914624
- 24. Guskov A.V., Gagarin P.G., Guskov V.N. et al. // Russ. J. Phys. Chem. A. 2022. V. 96. P. 1195. https://doi.org/10.1134/S0036024422060103
- 25. Zvereva I.A., Shelyapina M.G., Chislov M. et al. // J. Therm. Anal. Calorim. 2022. V. 147. P. 6147. https://doi.org/10.1007/s10973-021-10947-4
- 26. Kosova D.A., Provotorov D.I., Kuzovchikov S.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 752. https://doi.org/10.1134/S0036023620050125
- 27. Samoshkin D.A., Agazhanov A.Sh., Stankus S.V. // J. Phys.: Conf. Ser. 2021. V. 2119. P. 012135. https://doi.org/10.1088/1742-6596/2119/1/012135
- 28. Smirnova N.N., Markin A.V., Abarbanel N.V. et al. // Russ. J. Phys. Chem. A. 2021. V. 95. P. 2387. https://doi.org/10.1134/S0036024421120219
- 29. Matskevich N.I., Wolf Th., Le Tacon M. et al. // J. Therm. Anal. Calorim. 2017. V. 130. P. 1125. https://doi.org/10.1007/s10973-017-6493-z
- 30. Drebushchak V.A., Isaenko L.I., Lobanov S.I. et al. // J. Therm. Anal. Calorim. 2017. V. 129. P. 103. https://doi.org/10.1007/s10973-017-6176-9
- 31. Tkachev E.N., Matskevich N.I., Samoshkin D.A. et al. // Phys. B: Cond. Matter. 2021. V. 612. P. 412880. https://doi.org/10.1016/j.physb.2021.412880
- 32. Khan A., Khan S., Kim H.J. et al // Optik. 2021. V. 242. P. 167035. https://doi.org/10.1016/j.ijleo.2021.167035
- 33. Glushko V.P. Termicheskie Konstanty Veshchestv (Thermal Constants of Substances), Moscow: VINITI, 1965–1982. № 1–10.
- 34. O’Hare P.A.G., Hoekstra H.R. // J. Chem. Thermodyn. 1973. V. 5. P. 851. https://doi.org/10.1016/S0021-9614 (73)80047-3
- 35. Musikhin A.E., Naumov V.N., Bespyatov M.A. et al. // J. Alloys Compd. 2015. V. 639. P. 145. https://doi.org/10.1016/j.jallcom.2015.03.159
- 36. Orborne D.W., Flotov H.E., Hoekstra H.R. // J. Chem. Thermodyn. 1974. V. 6. P. 179. https://doi.org/10.1016/0021-9614 (74)90260-2
