- PII
- 10.31857/S0044457X22601432-1
- DOI
- 10.31857/S0044457X22601432
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 1
- Pages
- 10-16
- Abstract
- An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+] ) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of (1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.
- Keywords
- октагидротриборат-анион полимерная мембрана октагидротриборат тетрадециламмония
- Date of publication
- 01.01.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 50
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