- PII
- 10.31857/S0044457X22601419-1
- DOI
- 10.31857/S0044457X22601419
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 2
- Pages
- 248-255
- Abstract
- Solid–liquid equilibria in the system H2O–Gd(NO3)3 were measured from –20 to 70°C using the isothermal saturation method. The Pitzer–Simonson–Clegg thermodynamic model was implemented to obtain the temperature dependence of Gd(NO3)3⋅6H2O solubility constant, to calculate salt solubility and to construct a phase diagram of the system from eutectic point to hydrate melting. Thermochemical properties of gadolinium nitrate aqueous solutions, such as dilution enthalpies and heat capacities, were assessed also. The model has shown to be reliable for phase equilibria calculation from –35 to 90°C and from 0 up to ~15 mol % of salt as well as the thermodynamic properties of Gd(NO3)3 aqueous solutions at room temperature and around it.
- Keywords
- растворимость растворы электролитов нитрат гадолиния термодинамическое моделирование модель Питцера–Симонсона–Клегга
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 11
References
- 1. Поляков Е.Г., Нечаев А.В., Смирнов А.В. Металлургия редкоземельных металлов: учебное пособие для вузов. 2-е изд., стер. М.: Изд-во Юрайт, 2021. 501 с.
- 2. Крюков В.А., Толстов А.В., Самсонов Н.Ю. // ЭКО. 2016. № 11. С. 5.
- 3. Zhang J., Zhao B., Schreiner B. Separation Hydrometallurgy of Rare Earth Elements, Springer Cham, 2016. 259 p. https://doi.org/10.1007/978-3-319-28235-0
- 4. Turanov A.N., Karandashev V.K., Burmii Z.P. et al. // Russ. J. Gen. Chem. 2022. V. 92. № 3. P. 418. https://doi.org/10.1134/S1070363222030082
- 5. Arkhipin A.S., Nesterov A.V., Kovalenko N.A. et al. // J. Chem. Eng. Data. 2021. V. 66. № 4. P. 1694. https://doi.org/10.1021/acs.jced.0c01006
- 6. Radhika S., Kumar B.N., Kantam M.L. et al. // Sep. Purif. Technol. 2010. V. 75. № 3. P. 295. https://doi.org/10.1016/j.seppur.2010.08.018
- 7. Kurdakova S.V., Kovalenko N.A., Petrov V.G. et al. // J. Chem. Eng. Data. 2017. V. 62. № 12. P. 4337. https://doi.org/10.1021/acs.jced.7b00696
- 8. Chatterjee S., Campbell E.L., Neiner D. et al. // J. Chem. Eng. Data. 2015. V. 60. № 10. P. 2974. https://doi.org/10.1021/acs.jced.5b00392
- 9. Maksimov A.I., Kovalenko N.A., Uspenskaya I.A. // Calphad. 2019. V. 67. P. 101683. https://doi.org/10.1016/j.calphad.2019.101683
- 10. Guignot S., Lassin A., Christov C. et al. // J. Chem. Eng. Data. 2019. V. 64. № 1. P. 345. https://doi.org/10.1021/acs.jced.8b00859
- 11. Moiseev A.E., Dzuban A.V., Gordeeva A.S. et al. // J. Chem. Eng. Data. 2016. V. 61. № 9. P. 3295. https://doi.org/10.1021/acs.jced.6b00357
- 12. Scandium, Yttrium, Lanthanum and Lanthanide Nitrates // IUPAC. Solubility Data Ser / Eds. Siekierski S., Mioduski T., Salomon M. N.Y.: Pergamon Press Inc., 1983. P. 15.
- 13. Moret R. // Thèse doctorat, l’Université Lausanne, 1963.
- 14. Rard J.A., Shiers L.E., Heiser D.J. et al. // J. Chem. Eng. Data. 1977. V. 22. № 3. P. 337. https://doi.org/10.1021/je60074a015
- 15. Libuś Z., Sadowska T., Trzaskowski J. // J. Chem. Thermodyn. 1979. V. 11. № 12. P. 1151. https://doi.org/10.1016/0021-9614 (79)90107-1
- 16. Spedding F.H., Derer J.L., Mohs M.A. et al. // J. Chem. Eng. Data. 1976. V. 21. № 4. P. 474. https://doi.org/10.1021/je60071a028
- 17. Spedding F.H., Baker J.L., Walters J.P. // J. Chem. Eng. Data. 1979. V. 24. № 4. P. 298. https://doi.org/10.1021/je60083a033
- 18. Hakin A.W., Liu J.L., Erickson K. et al. // J. Chem. Thermodyn. 2005. V. 37. № 2. P. 153. https://doi.org/10.1016/j.jct.2004.08.010
- 19. Pitzer K.S., Peterson J.R., Silvester L.F. // J. Solut. Chem. 1978. V. 7. № 1. P. 45. https://doi.org/10.1007/BF00654217
- 20. Dzuban A.V., Galstyan A.A., Kovalenko N.A. et al. // Russ. J. Phys. Chem. A. 2021. V. 95. № 12. P. 2394. https://doi.org/10.1134/S0036024421120074
- 21. May P.M., Rowland D. // J. Chem. Eng. Data. 2017. P. Acs. Jced.6b01055 https://doi.org/10.1021/acs.jced.6b01055
- 22. Clegg S.L., Pitzer K.S. // J. Phys. Chem. 1992. V. 96. № 8. P. 3513. https://doi.org/10.1021/j100187a061
- 23. Clegg S.L., Pitzer K.S., Brimblecombe P. // J. Phys. Chem. 1992. V. 96. № 23. P. 9470. https://doi.org/10.1021/j100202a074
- 24. Pitzer K.S., Simonson J.M. // J. Phys. Chem. 1986. V. 90. № 13. P. 3005. https://doi.org/10.1021/j100404a042
- 25. Baes C.F., Mesmer R.E. The hydrolysis of cations. N.Y.: Wiley, 1976. 489 p.
- 26. Rizkalla E.N., Choppin G.R. Hydration and hydrolysis of lanthanides // Handb. Phys. Chem. Rare Earths. V. 15. North Holland, 1991.
- 27. Spedding F.H., Pikal M.J., Ayers B.O. // J. Phys. Chem. 1966. V. 70. № 8. P. 2440. https://doi.org/10.1021/j100880a003
- 28. Revised Release on the IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam (The revision only relates to the extension of region 5 to 50 MPa), The International Association for the Properties of Water and Steam, Lucerne, Switzerland, 2007.
- 29. Criss C.M., Millero F.J. // J. Solut. Chem. 1999. V. 28. № 7. P. 849. https://doi.org/10.1023/A:1021732214671
- 30. Kosova D.A., Voskov A.L., Kovalenko N.A. et al. // Fluid Phase Equilib. 2016. V. 425. P. 312. https://doi.org/10.1016/j.fluid.2016.06.021
- 31. CRC Handbook of Chemistry and Physics / Eds. Rumble J.R., Bruno T.J., Doa M.J. Boca Raton: CRC Press/Taylor & Francis Group, 2021.
- 32. Quill L.L., Robey R.F. // J. Am. Chem. Soc. 1937. V. 59. № 6. P. 1071. https://doi.org/10.1021/ja01285a031
