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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

HYDROTHERMAL SYNTHESIS OF KCe(PO) · хHO AND ANALYSIS OF ITS PHOTOPROTECTIVE PROPERTIES

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PII
S3034560XS0044457X25080038-1
DOI
10.7868/S3034560X25080038
Publication type
Article
Status
Published
Authors
T.O. Kozlova
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    National Research University Higher School of Economics
D. N. Vasilyeva
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    National Research University Higher School of Economics
I. V. Savintseva
  • Affiliation: Institute of Theoretical and Experimental Biophysics of the Russian Academy of Sciences
A. L. Popov
  • Affiliation: Institute of Theoretical and Experimental Biophysics of the Russian Academy of Sciences
N. P. Simonenko
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
D. A. Kozlov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 70 / Issue number 8
Pages
1004-1013
Abstract
A new method for obtaining KCe(PO) ∙ xHO (s. g. I4/amd, a= b= 6.8300(2), c= 17.8488(4) Å, V= 832.63(4) Å, Z= 4) under hydrothermal conditions has been developed. It has been established that the thermolysis of this compound proceeds through three stages of mass loss with the formation of CePO и KPO as intermediate products, which upon further heating form a mixture of CePO and KCe(PO). The calculated values of the sun protection factor and UVA protection factor for KCe(PO) ∙ xHO were 2.1 and 2.0, respectively. In relation to the human keratinocyte cell line (HaCaT), a photoprotective effect of KCe(PO) ∙ xHO was recorded. For the first time, the photoactive properties of KCe(PO) and KCe(PO) ∙ хHO in the decomposition reaction of methylene blue were evaluated. A significant slowdown in the decomposition reaction of an organic dye was demonstrated when using KCe(PO) ∙ хHO.
Keywords
фосфаты церия(IV) структура термолиз защита от УФ-излучения солнцезащитный фактор (SPF)
Date of publication
15.02.2026
Year of publication
2026
Number of purchasers
0
Views
70

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