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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

INTERCALATION OF - AND -METAL MALONATES INTO LAYERED YTTRIUM HYDROXIDE

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PII
S3034560XS0044457X25080024-1
DOI
10.7868/S3034560X25080024
Publication type
Article
Status
Published
Authors
E.D. Sheichenko
  • Affiliation:
    Karnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
    National Research University Higher School of Economics
V.M. Gumenyk
  • Affiliation:
    Karnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
    Faculty of Materials Science, Lomonosov Moscow State University
A.D. Yapryntsev
  • Affiliation: Karnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 70 / Issue number 8
Pages
995-1003
Abstract
Methods for obtaining hybrid compounds based on layered yttrium hydroxide intercalated with malonate complexes of d-metals (Cr, Fe, Ni, Cu, Zn) and f-metals (Eu, Tb) have been developed. The influence of temperature during anion-exchange reactions and the nature of the intercalated metal cations on the orientation and coordination modes of malonate anions within the interlayer space of yttrium layered hydroxide was established. The content of d- and f-metal cations in the resulting hybrid compounds increases in the following order of intercalated cations: Tb, Ni, Zn, Cu, Cr, Eu, Fe. These results highlight the potential of yttrium layered hydroxide intercalated with malonate anions as a platform for designing novel hybrid materials based on d- and f-metals.
Keywords
слоистые гидроксиды РЗЭ малоновая кислота гибридные материалы
Date of publication
11.12.2025
Year of publication
2025
Number of purchasers
0
Views
17

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