- PII
- S3034560X25100105-1
- DOI
- 10.7868/S3034560X25100105
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 70 / Issue number 10
- Pages
- 1324-1332
- Abstract
- The reaction of bis(dioxane) and bis(tetrahydropyran) derivatives of iron(II) bis(dicarbollide) [8,8'-{О(СНСН)X}-3,3'-Fe(1,2-CBH)] (X = О, СН) with pyridine in an inert atmosphere has been studied. It was found that the ring-opening of oxonium cycles proceeds stepwise, with the formation of the corresponding mono- and dipyridinium iron(II) complexes. Using the bis(dioxane) dipyridinium derivative as an example, it was found that, when in solution, oxidation of the resulting products to the corresponding paramagnetic complexes of iron(III) is possible. This approach opens the way to obtain bifunctional iron bis(dicarbolide) derivatives with different substituents. The obtained compounds were characterized by multinuclear NMR and IR spectroscopy, as well as high-resolution mass spectrometry. The structure of the symmetrical dipyridinium iron(II) complex [8,8'-{СHNCHCHOCHCHO}2-3,3'-Fe(1,2-CBH)] was determined by single crystal X-ray diffraction.
- Keywords
- металлокарбораны бис(дикарболлид) железа циклические оксониевые производные синтез свойства нуклеофильное раскрытие пиридин
- Date of publication
- 01.10.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 71
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