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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Synthesis of granulated hydrophobic magnetic sorbents and composite sponges based on Fe3O4/Zn-Al-LDH for oil pollution removal

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PII
S0044457X25030165-1
DOI
10.31857/S0044457X25030165
Publication type
Article
Status
Published
Authors
N. P. Ivanov
  • Affiliation: Far Eastern Federal University
Volume/ Edition
Volume 70 / Issue number 3
Pages
445-454
Abstract
In this study, we present a novel surface modification approach for magnetic composite materials based on Fe3O4/Zn-Al layered double hydroxides (LDH) to enhance their hydrophobic properties. We have systematically investigated the interaction mechanisms between various surfactants (stearate, oleate, and sodium dodecyl sulfate) and the Fe3O4/Zn-Al-LDH surface. Our research examined how ethanol-mediated hydrophobization affects the material's porous and crystalline structure. We developed innovative synthesis routes for both granulated and sponge-like magnetic sorbents utilizing melamine-formaldehyde resin as a binding matrix. Under optimized conditions, the resulting Fe3O4-LDH-ST granulated sorbents and MEL-Fe3O4/LDH-ST sponge-like materials demonstrated exceptional oil sorption capacities of 0.60 and 21.36 g/g, respectively, combined with significant magnetic susceptibility, enhanced hydrophobicity, and excellent regeneration potential. These engineered materials show promise for marine oil spill remediation and environmental monitoring applications.
Keywords
нефтесорбенты слоистые двойные гидроксиды меланин-формальдегидная смола нанопористые материалы гидрофобность
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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