- PII
- S0044457X25030072-1
- DOI
- 10.31857/S0044457X25030072
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 70 / Issue number 3
- Pages
- 357-367
- Abstract
- The paper presents the synthesis of layered complex carbide of the composition (Cr,V)C using reactive spark plasma sintering (SPS-RS) and hydrothermal acid etching. Using SEM and TEM, a detailed study of the macro- and nano-structure at each stage of MAXene synthesis was carried out. The presence of characteristic features of the formation of two-dimensional carbide in the form of particles and fragments of a multilayer structure at the macro- and nanolevel was confirmed. Using EDS and XRD, the elemental and phase composition of the samples was studied, as a result it was found that the initial expected MAX-phase Cr2VAlC2 in the composition of the sample obtained by SPS is absent. At the same time, a phase of mixed bimetallic carbide (Cr,V)C was detected at all stages of synthesis, for which the crystal lattice parameters, including the unit cell volume, change significantly after acid etching. Obvious changes in the bulk and crystalline structure of (Cr,V)C correspond to the formation of two-dimensional nanoparticles in the synthesized material. The magnetic characteristics study showed that all samples have magnetic hysteresis with relatively low values of coercivity and remanence to saturation magnetization ratio. Low-temperature measurements showed a slight increase in magnetic moment with decreasing temperature for the sample obtained under reaction SPS conditions before acid etching in HF, without significant changes in magnetic behavior of the samples.
- Keywords
- двумерные материалы слоистые структуры магнитные материалы искровое плазменное спекание реакционное спекание ИПС
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
References
- 1. Cao Y., Xing G., Lin H. et al. // iScience. 2020. V. 23. № 10. P. 101614. https://doi.org/10.1016/j.isci.2020.101614
- 2. Zhang Q., Zhang Z., Li C. et al. // Chip. 2023. V. 2. № 4. P. 1. https://doi.org/10.1016/j.chip.2023.100059
- 3. Zhao H., Yun J., Li Z. et al. // Mater. Sci. Eng. R Reports. 2024. V. 161. P. 100873. https://doi.org/10.1016/j.mser.2024.100873
- 4. Telegin A.V., Namsaraev Z.Z., Bessonov V.D. et al. // Mod. Electron. Mater. 2024. V. 10. № 1. P. 51. https://doi.org/10.3897/j.moem.10.1.130290
- 5. Samardak A.Y., Sobirov M.I., Rogachev K.A. et al. // Small. 2024. V. 2401270. P. 1. https://doi.org/10.1002/smll.202401270
- 6. Lv L., Zhang P., Yang X. et al. // Surfaces and Interfaces. 2024. V. 44. № September 2023. P. 103678. https://doi.org/10.1016/j.surfin.2023.103678
- 7. Ahmadi B., Montazer M.N., Bozorg A. et al. // MXenes synthesis and characterization, in: MXenes as Surface-Active Adv. Mater., Elsevier. 2024, P. 33–61. https://doi.org/10.1016/B978-0-443-13589-7.00022-5
- 8. Simonenko E.P., Mokrushin A.S., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2024. P. 1. https://doi.org/10.1134/S0036023624601703
- 9. Alam M.S., Chowdhury M.A., Khandaker T. et al. // RSC Adv. 2024. V. 14. № 37. P. 26995. https://doi.org/10.1039/D4RA03714F
- 10. Shichalin O.O., Ivanov N.P., Seroshtan A.I. et al. // Ceram. Int. 2024. https://doi.org/10.1016/j.ceramint.2024.10.161
- 11. Simonenko E.P., Simonenko N.P., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 5. P. 705. https://doi.org/10.1134/S0036023622050187
- 12. Simonenko N.P., Glukhova O.E., Plugin I.A. et al. // Chemosensors 2023. V. 11. № 1. P. 1. https://doi.org/10.3390/chemosensors11010007
- 13. Ateş S., Süzer I., Erol A.M. et al. // ITU J. Metall. Mater. Eng. 2024. P. 16.
- 14. Simonenko E.P., Simonenko N.P., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 11. P. 1838. https://doi.org/10.1134/S0036023622601222
- 15. Mokrushin A.S., Nagornov I.A., Averin A.A. et al. // Chemosensors. 2023. V. 11. P. 142. https://doi.org/10.3390/chemosensors11020142
- 16. Simonenko E.P., Mokrushin A.S., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2024. P. 1. https://doi.org/10.1134/S0036023624600850
- 17. Simonenko E.P., Mokrushin A.S., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2024. https://doi.org/10.1134/S0036023624601727
- 18. He J., Frauenheim T. // J. Phys. Chem. Lett. 2020. V. 11. № 15. P. 6219. https://doi.org/10.1021/acs.jpclett.0c02007
- 19. Yadav A., Agarwal S., Khan S. // 2D Metal Carbides and Nitrides (MXenes) in Water Treatment, 2024. https://doi.org/10.1007/978-981-99-8010-9_5
- 20. Si C., Zhou J., Sun Z. // ACS Appl. Mater. Interfaces. 2015. V. 7. № 31. P. 17510. https://doi.org/10.1021/acsami.5b05401
- 21. He J., Lyu P., Sun L.Z. et al. // J. Mater. Chem. 2016. V. 4. № 27. P. 6500. https://doi.org/10.1039/c6tc01287f
- 22. He J., Frauenheim T. // J. Phys. Chem. Lett. 2020. V. 11. № 15. P. 6219. https://doi.org/10.1021/acs.jpclett.0c02007
- 23. Gutierrez-Ojeda S.J., Ponce-Pérez R., Guerrero-Sánchez J. et al. // Graphene 2D Mater. 2024. V. 9. № 1–2. P. 47. https://doi.org/10.1007/s41127-023-00068-0
- 24. Zou X., Liu H., Xu H. et al. // Mater. Today Energy. 2021. V. 20. P. 100668. https://doi.org/10.1016/j.mtener.2021.100668
- 25. Akinola O., Chakraborty I., Celio H. et al. // J. Mater. Res. 2021. V. 36. № 10. P. 1980. https://doi.org/10.1557/s43578-021-00258-7
