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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

BINDING OF GOLD(III) USING BISMUTH HEXAMETHYLENEDITHIOCARBAMATE: THE DOUBLE COMPLEXES OF [Au(SCNHm)][Bi(SCNHm)Cl] AND [Au(SCNHm)][Bi(SCNHm)Cl] (PREPARATION, CRYSTAL STRUCTURE, THERMAL BEHAVIOR AND ANTI-MYCOBACTERIAL ACTIVITY)

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PII
10.31857/S0044457X25040069-1
DOI
10.31857/S0044457X25040069
Publication type
Article
Status
Published
Authors
O. V. Loseva
  • Affiliation: Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 70 / Issue number 4
Pages
527-541
Abstract
It was established that during the interaction of bismuth hexamethylenedithiocarbamate (HmDtc) with a H[AuCl]/2M HCl solution, the individual forms of gold(III) binding in the solid phase are double complexes of [Au(SCNHm)][Bi(SCNHm)Cl] (I) and [Au(SCNHm)][Bi(SCNHm)Cl] (II). The structures of the obtained compounds include centrosymmetric/non-centrosymmetric (in I/II) complex cations of Au(III), as well as heteroleptic bismuth anions: both the mononuclear and binuclear, whose the ratio Bi : Dtc : Cl = 1:2:2/2:2:6 (I/II). The secondary S~S and S~Cl interactions that arise between these ionic structural units lead to the formation of three-dimensional supramolecular architectures. In the IR spectra of the compounds, the absorption bands of N–C(S)S bonds were assigned to HmDtc ligands in the inner sphere of Au(III) complex cations and Bi(III) anions. Thermal behavior of I and II was studied using the STA technique. The residual substance obtained after thermolysis of the samples is represented by metallic particles of a solid solution of bismuth in gold, coated with a layer of BiO. For complex I, a high level of anti-mycobacterial activity in vitro was revealed against the non-pathogenic strain Mycolicibacterium smegmatis.
Keywords
двойные дитиокарбаматно-хлоридные комплексы золота(III)-висмута(III) разнолигандные анионы висмута(III) структурная организация вторичные взаимодействия термическое поведение антибактериальная биоактивность
Date of publication
03.12.2024
Year of publication
2024
Number of purchasers
0
Views
3

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