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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

STRUCTURE AND PROPERTIES OF CATION-DEFICIENT BISMUTH AND VANADIUM CONTAINING CaMoO — BASED SOLID SOLUTIONS

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PII
10.31857/S0044457X25040052-1
DOI
10.31857/S0044457X25040052
Publication type
Article
Status
Published
Authors
A. V Klimova
  • Affiliation:
    Ural Federal University the first President of Russia B.N. Yeltsin
    The Zavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 70 / Issue number 4
Pages
516-526
Abstract
The article is devoted to the synthesis, determination of structural features, electrical conductivity and pigment characteristics of cation-deficient scheelite-type CaBiФMoVO solid solutions. Complex oxides were studied with X-ray diffraction and Raman spectroscopy. The concentration ranges of existence of different types and distortion of structure were discussed via the element ordering in 4 sublattice. The total electrical conductivity of the compounds was studied by impedance spectroscopy in the temperature range of 400–650°C. Arrhenius plots of electrical conductivity on the inverse temperature were constructed and analyzed. According to the diffuse light scattering data of powders, functions of color coordinates of the solid solutions were calculated.
Keywords
шеелит CaMoO KP-спектроскопия цветовые координаты электропроводность
Date of publication
16.01.2025
Year of publication
2025
Number of purchasers
0
Views
4

References

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