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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

PHOTOLYSIS AND PHOTODEGRADATION OF N-SUBSTITUTED PHTHALIMIDES WITH A CYMANTRENYL MOIETY

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PII
10.31857/S0044457X24120027-1
DOI
10.31857/S0044457X24120027
Publication type
Article
Status
Published
Authors
E. S. Kelbysheva
  • Affiliation: Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
M. V. Kozlova
  • Affiliation: Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 12
Pages
1677-1689
Abstract
The photochemical behavior of substituted phthalimides with carboxylate groups associated with the cymantrenyl fragment was studied by infrared spectroscopy (IR), nuclear magnetic resonance (NMR) spectroscopy, UV-visible spectroscopy and cyclic voltammetry (CVA). During the formation of hemilabile dicarbonyl chelate complexes, a sharp change in the electronic, electrochemical and optical properties of compounds is observed. According to the dynamic light scattering (DLS) method, further irradiation of solutions of these complexes leads to the formation of previously undescribed stable nanoparticles in liquid media containing manganese in two degrees of oxidation Mn2+/Mn1+ and a phthalimide fragment associated with a Cp-ring coordinated or uncoordinated with manganese(I).
Keywords
фталимид цимантрен комплексы фотохимия наночастицы
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
15

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