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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Mixed Yttrium and Dysprosium Lactates as First Example of Rare-Earth Hydrogen-Bonded Organic Framework Solid Solutions

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PII
10.31857/S0044457X24100057-1
DOI
10.31857/S0044457X24100057
Publication type
Article
Status
Published
Authors
M. V. Golikova
  • Affiliation:
    Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
    Lomonosov Moscow State University
Volume/ Edition
Volume 69 / Issue number 10
Pages
1391-1404
Abstract
For the first time, molecular solid solutions of yttrium and dysprosium lactates of [Y1-xDyx(C3H5O3)3(H2O)2] composition, where x = 0, 0.01, 0.1, 0.5, 0.8, and 1, have been obtained. These can be considered the first solid solutions of rare-earth hydrogen-bonded organic framework (M-HOF). The obtained compounds were analyzed using a set of instrumental methods, including X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), infrared (IR), and Raman spectroscopy. It has been shown that the unit cell volume of the lactate solid solutions linearly depends on their cationic composition. It has been established that changes in the cationic composition of the solid solutions result in a monotonic shift of the lines in the Raman spectra corresponding to Ln–O vibrations (151–158 cm–1). It has been demonstrated that the obtained compounds can be single-molecule magnets with an energy barrier of up to 108 K.
Keywords
мономолекулярные магнетики лактаты РЗЭ твердые растворы координационные полимеры
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
16

References

  1. 1. Deng W., Chen J., Yang L. et al. // Small. 2021. V. 17. № 35. P. 2101058. https://doi.org/10.1002/smll.202101058
  2. 2. Bang J., Kim H.-S., Kim D.H. et al. // J. Alloys Compd. 2022. V. 920. P. 166028. https://doi.org/10.1016/j.jallcom.2022.166028
  3. 3. Kusada K., Wu D., Kitagawa H. // Chem. – Eur. J. 2020. V. 26. № 23. P. 5105. https://doi.org/10.1002/chem.201903928
  4. 4. Бузанов Г.А., Нипан Г.Д. // Журн. неорган. химии. 2023. Т. 68. № 12. С. 1816. https://doi.org/10.31857/S0044457X23601566. Buzanov G.A., Nipan G.D. // Russ. J. Inorg. Chem. 2023. V. 68. № 12. P. 1834. https://doi.org/10.1134/S0036023623602337
  5. 5. Гуськов А.В., Гагарин П.Г., Гуськов В.Н. и др. // Журн. неорган. химии. 2023. Т. 68. № 11. С. 1599. https://doi.org/10.31857/S0044457X23601128
  6. 6. Эллерт О.Г., Попова Е.Ф., Кирдянкин Д.И. и др. // Журн. неорган. химии. 2023. Т. 68. № 10. С. 1339. https://doi.org/10.31857/S0044457X23600937
  7. 7. Lusi M. // CrystEngComm. 2018. V. 20. № 44. P. 7042. https://doi.org/10.1039/C8CE00691A
  8. 8. Tsunashima R. // CrystEngComm. 2022. V. 24. № 7. P. 1309. https://doi.org/10.1039/D1CE01632F
  9. 9. Chen J., Gao H., Tao Z. et al. // Coord. Chem. Rev. 2023. V. 485. P. 215121. https://doi.org/10.1016/j.ccr.2023.215121
  10. 10. Newsome W.J., Ayad S., Cordova J. et al. // J.Am. Chem. Soc. 2019. V. 141. № 28. P. 11298. https://doi.org/10.1021/jacs.9b05191
  11. 11. Wong S.N., Chen Y.C.S., Xuan B. et al. // CrystEngComm. 2021. V. 23. № 40. P. 7005. https://doi.org/10.1039/D1CE00825K
  12. 12. Wei W., He L., Han G. et al. // Coord. Chem. Rev. 2024. V. 507. P. 215760. https://doi.org/10.1016/j.ccr.2024.215760
  13. 13. Wang H.-L., Ma X.-F., Zhu Z.-H. et al. // Inorg. Chem. Front. 2019. V. 6. № 10. P. 2906. https://doi.org/10.1039/C9QI00582J
  14. 14. Сартакова А.В., Макаренко А.М., Куратьева Н.В. и др. // Журн. неорган. химии. 2023. Т. 68. № 9. С. 1217. https://doi.org/10.31857/S0044457X23600718
  15. 15. Li Y.-L., Wang H.-L., Zhu Z.-H. et al. // iScience. 2022. V. 25. № 11. P. 105285. https://doi.org/10.1016/j.isci.2022.105285
  16. 16. Пушихина О.С., Карпова Е.В., Царев Д.А. и др. // Журн. неорган. химии. 2023. Т. 68. № 9. С. 1324. https://doi.org/10.31857/S0044457X23601189
  17. 17. Rozes L., Sanchez C. // Chem. Soc. Rev. 2011. V. 40. № 2. P. 1006. https://doi.org/10.1039/c0cs00137f
  18. 18. Zhu Z.-H., Wang H.-L., Zou H.-H. et al. // Dalton Trans. 2020. V. 49. № 31. P. 10708. https://doi.org/10.1039/D0DT01998D
  19. 19. An Y., Lv X., Jiang W. et al. // Green Chem. Eng. 2024. V. 5. № 2. P. 187. https://doi.org/10.1016/j.gce.2023.07.004
  20. 20. Li Y.-L., Wang H.-L., Chen Z.-C. et al. // Chem. Eng. J. 2023. V. 451. P. 138880. https://doi.org/10.1016/j.cej.2022.138880
  21. 21. Lusi M. // Cryst. Growth Des. 2018. V. 18. № 6. P. 3704. https://doi.org/10.1021/acs.cgd.7b01643
  22. 22. Adams C.J., Haddow M.F., Lusi M. et al. // Proc. Natl. Acad. Sci. 2010. V. 107. № 37. P. 16033. https://doi.org/10.1073/pnas.0910146107
  23. 23. Bünzli J.-C.G., Piguet C. // Chem. Rev. 2002. V. 102. № 6. P. 1897. https://doi.org/10.1021/cr010299j
  24. 24. Wang H.-L., Zhu Z.-H., Peng J.-M. et al. // J. Clust. Sci. 2022. V. 33. № 4. P. 1299. https://doi.org/10.1007/s10876-021-02084-7
  25. 25. Chen R., Chen C.-L., Zhang H. et al. // Sci. China Chem. 2024. V. 67. № 2. P. 529. https://doi.org/10.1007/s11426-023-1847-x
  26. 26. Zhang L., Xie Y., Xia T. et al. // J. Rare Earths. 2018. V. 36. № 6. P. 561. https://doi.org/10.1016/j.jre.2017.09.018
  27. 27. Cui Y., Xu H., Yue Y. et al. // J. Am. Chem. Soc. 2012. V. 134. № 9. P. 3979. https://doi.org/10.1021/ja2108036
  28. 28. Yoshinari N., Konno T. // Coord. Chem. Rev. 2023. V. 474. P. 214850. https://doi.org/10.1016/j.ccr.2022.214850
  29. 29. Yapryntsev A.D., Baranchikov A.E., Churakov A.V. et al. // RSC Adv. 2021. V. 11. № 48. P. 30195. https://doi.org/10.1039/D1RA05923H
  30. 30. Голикова М.В., Япрынцев А.Д., Цзя Ч. и др. // Журн. неорган. химии. 2023. Т. 68. № 10. С. 1422. https://doi.org/10.31857/S0044457X23601050. Golikova M.V., Yapryntsev A.D., Jia Z. et al. // Russ. J. Inorg. Chem. 2023. V. 68. № 10. P. 1414. https://doi.org/10.1134/S0036023623601800
  31. 31. Cruz-Navarro A., Hernández-Romero D., Flores-Parra A. et al. // Coord. Chem. Rev. 2021. V. 427. P. 213587. https://doi.org/10.1016/j.ccr.2020.213587
  32. 32. Yin X., Deng L., Ruan L. et al. // Materials. 2023. V. 16. № 9. P. 3568. https://doi.org/10.3390/ma16093568
  33. 33. Goodwin C.A.P. // Dalton Trans. 2020. V. 49. № 41. P. 14320. https://doi.org/10.1039/D0DT01904F
  34. 34. Manna F., Oggianu M., Avarvari N. et al. // Magnetochemistry. 2023. V. 9. № 7. P. 190. https://doi.org/10.3390/magnetochemistry9070190
  35. 35. Ashebr T.G., Li H., Ying X. et al. // ACS Mater. Lett. 2022. V. 4. № 2. P. 307. https://doi.org/10.1021/acsmaterialslett.1c00765
  36. 36. Pointillart F., Bernot K., Golhen S. et al. // Angew. Chem. Int. Ed. 2015. V. 54. № 5. P. 1504. https://doi.org/10.1002/anie.201409887
  37. 37. Hernández-Paredes A., Cerezo-Navarrete C., Gómez García C.J. et al. // Polyhedron. 2019. V. 170. P. 476. https://doi.org/10.1016/j.poly.2019.06.004
  38. 38. Goryushina V.G., Savvin S.B., Romanova E.V. // Zh. Anal. Khim. 1963. https://www.osti.gov/biblio/4120261
  39. 39. Petrosyants S.P., Ilyukhin A.B., Efimov N.N. et al. // Russ. J. Coord. Chem. 2018. V. 44. № 11. P. 660. https://doi.org/10.1134/S1070328418110064
  40. 40. Prieto M. // Rev. Mineral. Geochem. 2009. V. 70. № 1. P. 47. https://doi.org/10.2138/rmg.2009.70.2
  41. 41. Powell J.E., Farrell J.L. // Ames Lab. Technical report, 1962. https://doi.org/10.2172/4749791
  42. 42. Jacob K.T., Raj S., Rannesh L. // Int. J. Mater. Res. 2007. V. 98. № 9. P. 776. https://doi.org/10.3139/146.101545
  43. 43. Kozachuk O., Meilikhov M., Yusenko K. et al. // Eur. J. Inorg. Chem. 2013. V. 2013. № 26. P. 4546. https://doi.org/10.1002/ejic.201300591
  44. 44. Vujovic D., Raubenheimer H.G., Nassimbeni L.R. // Eur. J. Inorg. Chem. 2004. V. 2004. № 14. P. 2943. https://doi.org/10.1002/ejic.200300794
  45. 45. Yeung H.H. ‐M., Li W., Saines P.J. et al. // Angew. Chem. Int. Ed. 2013. V. 52. № 21. P. 5544. https://doi.org/10.1002/anie.201300440
  46. 46. Zakharov B.A., Gribov P.A., Matvienko A.A. et al. // Z. Für Krist. – Cryst. Mater. 2017. V. 232. № 11. P. 751. https://doi.org/10.1515/zkri-2016-2038
  47. 47. Zurawski A., Mai M., Baumann D. et al. // Chem. Commun. 2011. V. 47. № 1. P. 496. https://doi.org/10.1039/C0CC02093A
  48. 48. Soares-Santos P.C.R., Cunha-Silva L., Paz F.A.A. et al. // Cryst. Growth Des. 2008. V. 8. № 7. P. 2505. https://doi.org/10.1021/cg800153a
  49. 49. Serre C., Millange F., Thouvenot C. et al. // J. Mater. Chem. 2004. V. 14. № 10. P. 1540. https://doi.org/10.1039/B312425H
  50. 50. Duan T.-W., Yan B. // J. Mater. Chem. С. 2014. V. 2. № 26. P. 5098. https://doi.org/10.1039/C4TC00414K
  51. 51. Zhang X., Li X., Gao W. et al. // Sustain. Energy Fuels. 2021. V. 5. № 16. P. 4053. https://doi.org/10.1039/D1SE00658D
  52. 52. Ronda‐Lloret M., Pellicer‐Carreño I., Grau‐Atienza A. et al. // Adv. Funct. Mater. 2021. V. 31. № 29. P. 2102582. https://doi.org/10.1002/adfm.202102582
  53. 53. Shannon R.D. // Acta Crystallogr., Sect. A. 1976. V. 32. № 5. P. 751. https://doi.org/10.1107/S0567739476001551
  54. 54. Silva E.N., Moura M.R., Ayala A.P. et al. // J. Raman Spectrosc. 2009. V. 40. № 8. P. 954. https://doi.org/10.1002/jrs.2207
  55. 55. Kaminskii A.A., Bohat L., Becker P. et al. // Phys. Status Solidi A. 2004. V. 201. № 14. P. 3200. https://doi.org/10.1002/pssa.200406893
  56. 56. Kartha V.B., Venkateswaran S. // Spectrochim. Acta, Part Mol. Spectrosc. 1981. V. 37. № 11. P. 927. https://doi.org/10.1016/0584-8539 (81)80017-7
  57. 57. Yang Y., Zhang Q., Luo L. // J. Common Met. 1989. V. 148. № 1–2. P. 187. https://doi.org/10.1016/0022-5088 (89)90026-X
  58. 58. Mariscal-Becerra L., Acosta-Najarro D., Falcony-Guajardo C. et al. // J. Nanophotonics. 2018. V. 12. № 2. P. 1. https://doi.org/10.1117/1.JNP.12.026018
  59. 59. Artini C., Carnasciali M.M., Plaisier J.R. et al. // Solid State Ionics. 2017. V. 311. P. 90. https://doi.org/10.1016/j.ssi.2017.09.016
  60. 60. White W.B., Keramidas V.G. // Spectrochim. Acta, Part Mol. Spectrosc. 1972. V. 28. № 3. P. 501. https://doi.org/10.1016/0584-8539 (72)80237-X
  61. 61. El-Habib A., Brioual B., Zimou J. et al. // Mater. Sci. Semicond. Process. 2024. V. 176. P. 108287. https://doi.org/10.1016/j.mssp.2024.108287
  62. 62. Socrates G. // Infrared and Raman characteristic group frequencies. Tables and charts, 2001.
  63. 63. Maiwald M.M., Müller K., Heim K. et al. // New J. Chem. 2020. V. 44. № 39. P. 17033. https://doi.org/10.1039/D0NJ04291A
  64. 64. Cassanas G., Morssli M., Fabrègue E. et al. // J. Raman Spectrosc. 1991. V. 22. № 7. P. 409. https://doi.org/10.1002/jrs.1250220709
  65. 65. Mink J., Skripkin M.Yu., Hajba L. et al. // Spectrochim. Acta, Part A: Mol. Biomol. Spectrosc. 2005. V. 61. № 7. P. 1639. https://doi.org/10.1016/j.saa.2004.11.030
  66. 66. Petrosyants S.P., Ilyukhin A.B., Babeshkin K.A. et al. // Russ. J. Coord. Chem. 2019. V. 45. № 8. P. 592. https://doi.org/10.1134/S1070328419080062
  67. 67. Петросянц С.П., Бабешкин К.А., Илюхин А.Б. и др. // Коорд. химия. 2021. Т. 47. № 4. С. 208. https://doi.org/10.31857/S0132344X2104006X
  68. 68. Новиков В.В., Нелюбина Ю.В. // Успехи химии. 2021. Т. 90. № 10. С. 1330.
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