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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Preparation and chemosensor properties of nano–composite obtained by hydrothermal modification of Ti2CTx by hierarchically organised Co(CO3)0.5 (OH) ⋅ 0.11H2O

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PII
10.31857/S0044457X24090146-1
DOI
10.31857/S0044457X24090146
Publication type
Article
Status
Published
Authors
E. P. Simonenko
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 9
Pages
1341-1352
Abstract
The process of modification of Ti2CTx MXene multilayer by hydrothermal synthesis of bulk hierarchically organized formations of Co(CO3)0.5(OH)⋅0.11H2O has been studied. It is shown that under the chosen conditions MXene is partially oxidized with the formation of aggregates of titanium dioxide nanoparticles with a diameter of ~3–10 nm on its surface. The sensing properties of the obtained composite material at room temperature and relative humidity 65±3% to a wide range of gaseous analytes (50 ppm CO, benzene, acetone, ethanol, 2500 ppm H2, CH4, 5% O2 and 40 ppm NH3, NO2) were investigated. Increased sensitivity was found for the detection of 40 ppm NH3 and NO2: the responses were -91 and -63%, respectively. Some aspects of the detection mechanism are discussed. The results obtained show promising modification of multilayer MXene with semiconducting metal oxides and hierarchically formed bulk formations in order to improve its chemoresistive properties.
Keywords
максен композит хеморезистивный газовый сенсор микроплоттерная печать
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
15

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