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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

GeTe–Bi2Te3–Te System

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PII
10.31857/S0044457X24080079-1
DOI
10.31857/S0044457X24080079
Publication type
Article
Status
Published
Authors
U. R. Bairamova
  • Affiliation:
    Baku State University
    Institute of Catalysis and Inorganic Chemistry
    Azerbaijan State University of Economics
Volume/ Edition
Volume 69 / Issue number 8
Pages
1144-1154
Abstract
Alloys of the GeTe–Bi2Te3–Te system, synthesized using a special technique that makes it possible to obtain them in a state as close as possible to equilibrium, have been studied using the methods of differential thermal and X-Ray diffraction analysis, as well as scanning electron microscopy. A solid-phase equilibria diagram, a projection of the liquidus surface, some polythermal sections and an isothermal section at 300 K of the phase diagram were constructed. The fields of primary crystallization of phases, types and coordinates of non— and monovariant equilibria are determined. It has been established that monovariant equilibria on curves emanating from the peritectic and eutectic points of the GeTe–Bi2Te3 boundary system undergo transformations at certain transition points. Near the tellurium corner of the concentration triangle, a cascade of invariant transition reactions has been identified, characterizing the joint crystallization of two-phase mixtures of telluride phases and elemental tellurium.
Keywords
теллуриды германия-висмута материалы с фазовой памятью топологический изолятор фазовая диаграмма тетрадимитоподобные слоистые фазы
Date of publication
15.08.2024
Year of publication
2024
Number of purchasers
0
Views
44

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