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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Di- and Octanuclear Iodoantimonates(III) with 1,2-Dimethylpyridinium and 3-Bromo-1-Ethyllpyridinium: Crystal Structure and Physico-Chemical Properties

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PII
10.31857/S0044457X24080053-1
DOI
10.31857/S0044457X24080053
Publication type
Article
Status
Published
Authors
N. A. Korobeinikov
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
    Irkutsk Favorsky Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 69 / Issue number 8
Pages
1128-1134
Abstract
By the reaction of SbI3 and iodides of the corresponding cations in organic solvents, two new antimony complexes were obtained — (3-Br-1-EtPy)3[Sb2I9] (1), (1,2-MePy)4[Sb8I28] (2). The features of the crystal structure of the compounds were determined by X-ray diffraction. The complexes are thermally stable up to at least 200°C and have a band gap of about 2.2 eV.
Keywords
сурьма галогенидные комплексы кристаллическая структура комплексные соединения
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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