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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Synthesis and thermal transformations of tungstenphosphatemetallate complexes with hexamethylenetetramine

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PII
10.31857/S0044457X24070118-1
DOI
10.31857/S0044457X24070118
Publication type
Article
Status
Published
Authors
N. S. Lozinskii
  • Affiliation: Litvinenko Institute of Physical Organic and Coal Chemistry
Volume/ Edition
Volume 69 / Issue number 7
Pages
1029-1038
Abstract
The results of the synthesis and identification of complex compounds of hexamethylenetetramine (CH2)6N4 (HMTA) with tungstenphosphatemetallates are presented. The processes and crystalline products of thermal decomposition of compounds with the general formula: Cat5[PW11O39Z(HMTA)] ∙ nH2O, Cat=Na+, NH4+; Z=Co2+, Ni2+, Zn2+; n = 10–13 and the schemes for their thermolysis were established. It has been shown that ammonium salts during thermolysis form phases of the composition ZO ∙ 0.5P2O5 ∙ 11WO3 or Z6/73P6/73W66/73O3 with the structure of phosphotungsten bronze. The decomposition products of sodium salts are a mixture of phases with the structures of sodium tungstates Na2W2O7 and Na2W4O13. The research results can be used to predict thermal transformations and the composition of thermolysis products of similar complexes of HMTA and tungstenphosphatemetallates of other 3d-elements.
Keywords
гетерополиоксометаллаты гексаметилентетрамин термический анализ продукты термолиза вольфрамовая бронза
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
12

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