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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Polymeric iodobismuthates Cat{[BiI4]} with pyridinium-derived cations: structure and properties

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PII
10.31857/S0044457X24070071-1
DOI
10.31857/S0044457X24070071
Publication type
Article
Status
Published
Authors
I. A. Shentseva
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
    Irkutsk Favorsky Institute of Chemistry SB RAS
Volume/ Edition
Volume 69 / Issue number 7
Pages
999-1005
Abstract
Two novel bismuth(III) iodide complexes – (1,3,4-MePy){[BiI4]} (1) и (3-Br-1-MePy){[BiI4]} (2)) – were synthesized by the reaction of iodides of corresponding cations with BiI3 in organic solvents. Crystal structure of the compounds was determined by X-ray diffraction; For both complexes, the thermal stability was studied, and the optical band gap values were experimentally estimated.
Keywords
кристаллическая структура висмут галогенидные комплексы комплексные соединения
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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