RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Structure, Adsorptive and Photocatalytic Properties of Porous ZnO Nanopowders Modified by Oxide Compounds of Manganese

PII
10.31857/S0044457X24030128-1
DOI
10.31857/S0044457X24030128
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 69 / Issue number 3
Pages
385-393
Abstract
Porous nanocomposites based on oxide compounds of zinc and manganese are synthesized and their structure, morphology, spectral and photocatalytic properties are studied. It is shown that the resulting porous oxide composites have photocatalytic properties and consist of ZnO, Mn3O4 and ZnMn2O4 nanocrystals with a size of 20–40 nm. The introduction of Mn2+ ions into the crystal lattice of ZnO causes a increase in the size of the unit cell of crystals. The band gap of the composites is 3.26 eV. The kinetics of photocatalytic decomposition in a Chicago Blue Sky dye solution is described by a pseudo-first order equation. In the presence of porous nanocomposites, the processes of oxidation of organic compounds proceed both on the surface of photocatalysts and in solution. The synthesized nanocomposites are promising for use in photocatalytic systems for water purification from organic contaminants.
Keywords
нанокомпозиты фотокатализ нанокристаллы оксиды
Date of publication
15.03.2024
Year of publication
2024
Number of purchasers
0
Views
47

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