Phase equilibria in the quasi–ternary Li2O–Mn2O3–Eu2O3 system

Buzanov, G. A.

doi:10.31857/S0044457X24010073

PII

10.31857/S0044457X24010073-1

DOI

10.31857/S0044457X24010073

Publication type

Article

Status

Published

Authors

G. A. Buzanov

Affiliation: Kurnakov Institute of General and Inorganic Chemistry of the RAS

Volume/ Edition

Volume 69 / Issue number 1

Pages

58-66

Abstract

Series of samples of quasi–ternary Li₂O–Mn₂O₃ – Eu₂O₃ system, synthesized from of precursors subjected to preliminary mechanochemical activation and annealed in air at temperatures of 700–1100°C have been systematically studied by powder X–ray diffraction(pXRD) and thermal analysis (TG–DSC) methods. The possibility of substituting Mn for Eu for the LiMn_2–xEu_xO₄ spinel phase is estimated. Within the framework of the Li–Mn–Eu concentration triangle, a subsolidus isobaric diagram and a projection of the liquidus surface of the Li–Mn–Eu–O system were constructed using models of polythermal phase diagrams of the LiEuO₂–LiMnO₂ and LiEuO₂–LiMn₂O₄ sections. The temperatures of eutectic equilibria with the participation of three crystalline phases and a melt were determined.

Keywords

фазовые равновесия твердые растворы шпинель многокомпонентные системы литий-ионные аккумуляторы

Date of publication

17.09.2025

Year of publication

2025

Number of purchasers

Views

References

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GOST	Buzanov G. Phase equilibria in the quasi–ternary Li₂O–Mn₂O₃–Eu₂O₃ system // Russian Journal of Inorganic Chemistry. – 2024. – V. 69. – Issue number 1 C. 58-66 . URL: https://inorgchemras.ru/10-31857-s0044457x24010073-1/?version_id=112934. DOI: 10.31857/S0044457X24010073
MLA	Buzanov, G. A "Phase equilibria in the quasi–ternary Li₂O–Mn₂O₃–Eu₂O₃ system." Russian Journal of Inorganic Chemistry. 69.1 (2024).:58-66. DOI: 10.31857/S0044457X24010073
APA	Buzanov G. (2024). Phase equilibria in the quasi–ternary Li₂O–Mn₂O₃–Eu₂O₃ system. Russian Journal of Inorganic Chemistry. vol. 69, no. 1, pp.58-66 DOI: 10.31857/S0044457X24010073

RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

Phase equilibria in the quasi–ternary Li₂O–Mn₂O₃–Eu₂O₃ system

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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

Phase equilibria in the quasi–ternary Li2O–Mn2O3–Eu2O3 system

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Phase equilibria in the quasi–ternary Li₂O–Mn₂O₃–Eu₂O₃ system