- PII
- 10.31857/S0044457X23601529-1
- DOI
- 10.31857/S0044457X23601529
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 12
- Pages
- 1691-1701
- Abstract
- Series of compounds Ni3 – xMTe2 (M = Sb, Sn; x = 0–1) were obtained by high-temperature sealed-tube synthesis and characterized by X-ray powder diffraction and 121Sb and 119Sn Mössbauer spectroscopy. For Ni3–xSnTe2, it was shown that, as х varies from 1 to 0, nickel is distributed over three possible sites, two of which give a total occupancy of 1 and have ordered vacancies. Meanwhile, for Ni3–xSbTe2 and х other than ~0.9–1.0, the vacancy ordering disappears. The temperature dependence of the presence or absence of vacancy ordering was established for Ni2SbTe2; the ordering disappears on heating above 600°C and appears again on cooling.
- Keywords
- слоистые фазы теллуриды никеля гетерометаллические связи твердофазный синтез порошковая дифракция мессбауэровская спектроскопия
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
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