- PII
- 10.31857/S0044457X23600561-1
- DOI
- 10.31857/S0044457X23600561
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 68 / Issue number 11
- Pages
- 1528-1536
- Abstract
- Interaction of rare-earth oxides (Pr, Tb, Er) with periodic acid or sodium iodate under hydrothermal conditions in the presence of Na2HPO4⋅12H2O leads to formation of complex NaLn(IO3)4 iodates. The compounds of Pr and Tb are reported for the first time. Single-crystal studies reveal that they are isostructural to the previously reported analogs of other rare-earths and adopt the non-centrosymmetric space group Сс. Polycrystalline samples generate a strong SHG signal above that of the potassium dihydrogen phosphate reference standard. They also exhibit wide optical transparency areas and high thermal stability.
- Keywords
- иодаты РЗЭ кристаллическая структура генерация второй гармоники
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
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