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RAS Chemistry & Material ScienceЖурнал неорганической химии Russian Journal of Inorganic Chemistry

  • ISSN (Print) 0044-457X
  • ISSN (Online) 3034-560X

Synthesis and Crystal Structures of (HL)2[B10Cl10]·3CH3CN (L = Bipy, Phen)

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PII
10.31857/S0044457X22602176-1
DOI
10.31857/S0044457X22602176
Publication type
Status
Published
Authors
T. М. Garaev
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 68 / Issue number 6
Pages
824-831
Abstract
Reactions of (Et3NH)2[B10Cl10] and organic ligands 2,2'-bipyridyl (Bipy) and 1,10-phenanthroline (Phen) in the acetonitrile–trifluoroacetic acid system have yielded compounds of composition (HL)2[B10Cl10]·3CH3CN (L = Bipy, Phen). The compounds have been characterized by IR spectroscopy, elemental analysis, and X-ray diffraction (CCDC nos. 2224377 and 2224378). It has been shown that in the presence of trifluoroacetic acid, protonation of organic ligands occurs with the formation of bipyridylium and phenanthrolinium salts, which are stabilized by the decachloro-closo-decaborate anion. It has been found that the cations participate in the formation of hydrogen bonds with the solvate molecules of acetonitrile, while only weak C–H…Cl and B–Cl…π interactions are observed for boron cluster anions.
Keywords
декахлор-<i>клозо</i>-декаборатный анион бипиридил фенантролин рентгеноструктурный анализ
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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